Damping estimation using free decays and ambient vibration tests

This paper studies the quality of modal damping ratios estimates based on ambient and free vibration tests using both numerical simulations and data collected on large Civil Engineering structures where both tests were performed. The simulated data allowed to study the influence of factors like non-proportional damping or proximity of natural frequencies on the quality of the estimates and also to illustrate the influence of the identification algorithms parameters on the accuracy of the results. The analysis of data collected on a cable-stayed bridge, on the suspended roof of a stadium and on a footbridge permitted to compare the results of both testing approaches in real applications where some factors that cannot be realistically included in the numerical simulations can play an important role. The processing of ambient vibration responses is performed with two output-only identification approaches: frequency domain decomposition and stochastic subspace identification methods. The numerically simulated and the measured free decays were analyzed with a simple method based on filters and fitting of exponential decays and also with the use of subspace models.     

Seed oils of ten traditional Portuguese grape varieties with interesting chemical and antioxidant properties

To increase the potential and better exploring of grape seeds that are an important wine-industrial waste, oils of ten traditional Portuguese grape varieties were evaluated in relation to their vitamin E content (tocopherols and tocotrienols), fatty acid profile, as well as, antioxidant properties. Our results showed that the grape-seed oils were a good source of γ-tocotrienol (499–1575 mg/kg), α-tocopherol (85.5–244 mg/kg) and α-tocotrienol (69–319 mg/kg). Concerning fatty acid profile, linoleic (C18:2cc), oleic (C18:1), palmitic (C16:0) and stearic (C18:0) acids were the predominant. Grape-seed oils demonstrated to be a good source of polyunsaturated fatty acids (PUFAs) (63.64–73.53%), whereas monounsaturated fatty acid (MUFA) and saturated fatty acid (SFA) ranged between 14.19–21.29% and 11.64–14.94%, respectively. Interesting values of DPPH and ABTS radical scavenging activities were also obtained. This study demonstrated that these seeds may be reused and their oils incorporated in other food products, taking into account the compounds with positive effects on human health that are present in their composition.     

Impact of different internal convection control strategies in a non-evacuated CPC collector performance

Over the last decade the technological advances observed in solar collector materials, namely better spectrally selective absorber coatings and ultra clear glass covers, contribute to performance improvements and translate into higher operational temperature ranges with higher efficiency values.While the use of Evacuated Tube Collectors (ETCs) is becoming widespread in the thermal conversion of solar energy, non-evacuated solar collectors still hold advantages at manufacturing, reliability and/or cost levels, making them interesting and competitive for a large range of applications, in particularly, in temperature ranges up to 80 °C. However, these advantages have not prevented the major drawback of these collectors when compared to ETCs: thermal losses due to internal convection which prevent their general use in the range of operating temperatures up to 150 °C.Insulation, double glazing or selective coatings can be used in non-evacuated collectors to reduce heat losses. To prevent internal convection losses in these solar collectors, different control strategies have been studied, such as the adoption of different inert gases within the collector cavity, physical barriers reducing air flow velocities over the absorber or cover surfaces or the use of concentration.In the present article, an assessment of adopting such internal convection control strategies in a CPC collector is presented. Each of the presented strategies is assessed in terms of the resulting collector optical and thermal characterization parameters and yearly collector yield. For this purpose, an integrated tool allowing the design, optical and thermal characterization of CPC collectors was developed. The results obtained provide valuable guidelines for anyone wishing to implement any of these strategies in a new collector design.     

Electrochemical mineralization of sodium dodecylbenzenesulfonate at boron doped diamond anodes

Results are reported of the electrochemical oxidation of sodium dodecylbenzenesulfonate (SDBS), a common surfactant, at boron-doped diamond anodes. The measured critical micelle concentration (CMC) for SDBS in water at 24 °C was almost 150 mg dm⁻³, but this decreased to almost 30 mg dm⁻³ in 0.1 M sodium sulfate. Cyclic voltammetry of a boron doped diamond (BDD) electrode in aqueous SDBS solutions exhibited oxidation current densities at very positive potentials; however, solutions of monomers at concentrations <CMC gave rise to higher current densities than in higher concentration solutions that formed micelles. Galvanostatic electrolyses, with samples analyzed for Total Organic Carbon (TOC) and Chemical Oxygen Demand (COD), were performed in an electrolytic flow cell without separator, operating in batch recycle mode, using solutions containing SDBS at initial concentrations of 25 and 250 ppm. SDBS in basic media (pH = 12) exhibited lower TOC removal rates than in acidic or neutral solutions, due to concurrent oxidation of dissolved carbonates at potentials less positive than required for water oxidation, as evident in cyclic voltammograms. Decreasing the [electrolyte]/[surfactant] ratio from 200 to 10 increased TOC removal rates. For solutions containing monomers, TOC removal rates also increased with flow rate in the second part of the electrolysis, corresponding to reaction of smaller, fragmented organic compounds. When COD removal from a solution containing SDBS micelles was mass transport controlled, current efficiencies were constant at ca. 50%, due to dimerisation of hydroxyl radical to H₂O₂ and its oxidation to dioxygen.     

Dried Tomato‐Flavored Probiotic Cream Cheese with Lactobacillus paracasei

Abstract: A dried tomato‐flavored probiotic cream cheese (P) containing Lactobacillus paracasei Lpc‐37 was developed for the purpose of this study. The same product, but without probiotic addition (C) was used as control. Lactococcus lactis subsp. lactis and Lactococcus lactis subsp. cremoris were used as lactic starter cultures. Chemical composition analyses and sensory tests were performed on days 1 and 7, respectively. Titratable acidity, pH value and L. paracasei population were determined every 7 d during the refrigerated storage (21 d) of the cream cheeses. The experiment and analyses were performed in triplicate, using standard methods. Probiotic population remained greater than 10⁷ CFU/g throughout the storage period, thereby characterizing the product as potentially probiotic. Cream cheeses C and P did not differ on the sensory tests, both obtaining good overall acceptance by the consumers, of which 82.6% stated that they certainly or probably would buy the product. Practical Application: Lactobacillus paracasei Lpc‐37 is a probiotic bacterium and clinical studies have shown that this microorganism beneficially affects its host. In general, dried tomato‐flavored products and cream cheese are products with good acceptance by the consumers. Thus, regular consumption of the probiotic cream cheese developed in this study may have positive effects on health and well being of people if incorporated into their diet.     

Production of Ti–13Nb–13Zr alloy for surgical implants by powder metallurgy

The Ti–13Nb–13Zr near-β alloy was developed aiming the replacement of the traditional Ti–6Al–4V alloy in surgical implants owing to its larger biocompatibility. Samples of this alloy were obtained using the blended elemental technique from hydrided powders. The isochronal sintering of the compacts for 2 h was carried out in the range 900–1,400 °C with a heating rate of 20 °C min⁻¹. In this work, the behavior of the elementary powders during sintering and the corresponding microstructural evolution were investigated. The alloy was characterized by means of scanning electron microscopy (SEM) in the backscattered mode, X-ray diffraction, and density measurements. The results indicate that the homogenization of the alloy is diffusion-controlled. With increasing temperature, homogenization of the alloy takes place and a fine plate-like α + β structure is found throughout the microstructure in temperatures above 1,300 °C. The process variables were defined aiming to minimize interstitial pick-up (C, O, and N) and avoiding intensive grain growth.     

洗发、护发用新型润肤剂的发泡、清洁及护理(续前)

2）香波洗涤条件 按照泡沫均质搅拌测试的要求备好香波样品，将样品加热至40℃后放入颗粒图像测量仪的玻璃贮液器。启动测量仪成像系统后，将发束放入配方液，浸泡约30s，随后清洗30s，风干。     

Fragility curve probabilistic model applied to durability and long term mechanical damage of masonry

In view of preserving the historical heritage, the deterioration processes of masonry materials and the long term damage of multiple leaf historic buildings is studied from an experimental and a numerical point of view. Durability tests and pseudo-creep tests have been carried out and interpreted through probabilistic models for the service life prediction. The precocious recognition of structural critical states will allow to design repair and strengthening interventions and to prevent total or partial failure of the constructions.